Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio

Liliana Ruiz-Vásquez; Lastenia Ruiz Mesia; Matías Reina-Artiles; M. López-Rodríguez; J. González-Platas; Cristina Giménez; Raimundo Cabrera; Azucena González-Coloma

doi:10.1016/j.phytol.2018.07.002

Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio

Liliana Ruiz-Vásquez, Lastenia Ruiz Mesia, Matías Reina-Artiles, M. López-Rodríguez, J. González-Platas, Cristina Giménez, Raimundo Cabrera, Azucena González-Coloma

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

8 Citas (Scopus)

Resumen

Sixteen compounds incluiding four benzofurans (1–4), three benzoic acid derivatives (6–8), one eremophilane (9), four diterpenes (10–13) and four pyrrolizidine alkaloids (14–17) were isolated from Senecio subcandidus, S. klugii and S. ayapatensis from Perú. Compounds 1–4 and 6–9 have not been previously reported as natural products. Their molecular structures were determined by NMR spectroscopic analysis, comparison with published NMR data and chemical transformations. The X-ray analysis of acetylated derivative 5 and compound 7 were also performed. Their insecticidal and antifungal activities were tested.

Idioma original	Inglés
Páginas (desde-hasta)	47-54
Número de páginas	8
Publicación	Phytochemistry Letters
Volumen	28
DOI	https://doi.org/10.1016/j.phytol.2018.07.002
Estado	Publicada - dic. 2018

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title = "Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio",

abstract = "Sixteen compounds incluiding four benzofurans (1–4), three benzoic acid derivatives (6–8), one eremophilane (9), four diterpenes (10–13) and four pyrrolizidine alkaloids (14–17) were isolated from Senecio subcandidus, S. klugii and S. ayapatensis from Per{\'u}. Compounds 1–4 and 6–9 have not been previously reported as natural products. Their molecular structures were determined by NMR spectroscopic analysis, comparison with published NMR data and chemical transformations. The X-ray analysis of acetylated derivative 5 and compound 7 were also performed. Their insecticidal and antifungal activities were tested.",

keywords = "Asteraceae, Benzofurans, Benzoic acid derivatives, Diterpenes, Pyrrolizidine alkaloids, Senecio",

author = "Liliana Ruiz-V{\'a}squez and {Ruiz Mesia}, Lastenia and Mat{\'i}as Reina-Artiles and M. L{\'o}pez-Rodr{\'i}guez and J. Gonz{\'a}lez-Platas and Cristina Gim{\'e}nez and Raimundo Cabrera and Azucena Gonz{\'a}lez-Coloma",

note = "Publisher Copyright: {\textcopyright} 2018 Phytochemical Society of Europe",

year = "2018",

month = dec,

doi = "10.1016/j.phytol.2018.07.002",

language = "English",

volume = "28",

pages = "47--54",

journal = "Phytochemistry Letters",

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TY - JOUR

T1 - Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio

AU - Ruiz-Vásquez, Liliana

AU - Ruiz Mesia, Lastenia

AU - Reina-Artiles, Matías

AU - López-Rodríguez, M.

AU - González-Platas, J.

AU - Giménez, Cristina

AU - Cabrera, Raimundo

AU - González-Coloma, Azucena

PY - 2018/12

Y1 - 2018/12

N2 - Sixteen compounds incluiding four benzofurans (1–4), three benzoic acid derivatives (6–8), one eremophilane (9), four diterpenes (10–13) and four pyrrolizidine alkaloids (14–17) were isolated from Senecio subcandidus, S. klugii and S. ayapatensis from Perú. Compounds 1–4 and 6–9 have not been previously reported as natural products. Their molecular structures were determined by NMR spectroscopic analysis, comparison with published NMR data and chemical transformations. The X-ray analysis of acetylated derivative 5 and compound 7 were also performed. Their insecticidal and antifungal activities were tested.

AB - Sixteen compounds incluiding four benzofurans (1–4), three benzoic acid derivatives (6–8), one eremophilane (9), four diterpenes (10–13) and four pyrrolizidine alkaloids (14–17) were isolated from Senecio subcandidus, S. klugii and S. ayapatensis from Perú. Compounds 1–4 and 6–9 have not been previously reported as natural products. Their molecular structures were determined by NMR spectroscopic analysis, comparison with published NMR data and chemical transformations. The X-ray analysis of acetylated derivative 5 and compound 7 were also performed. Their insecticidal and antifungal activities were tested.

KW - Asteraceae

KW - Benzofurans

KW - Benzoic acid derivatives

KW - Diterpenes

KW - Pyrrolizidine alkaloids

KW - Senecio

UR - http://www.scopus.com/inward/record.url?scp=85053330217&partnerID=8YFLogxK

U2 - 10.1016/j.phytol.2018.07.002

DO - 10.1016/j.phytol.2018.07.002

M3 - Article

AN - SCOPUS:85053330217

SN - 1874-3900

VL - 28

SP - 47

EP - 54

JO - Phytochemistry Letters

JF - Phytochemistry Letters

ER -

Benzofurans, benzoic acid derivatives, diterpenes and pyrrolizidine alkaloids from Peruvian Senecio

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